Functionalization of Synthesized Nanoporous Silica and Its Application in Malachite Green Removal from Contaminated Water

Bahman  Hassan-Zadeh; Reza  Rahmanian; Mohammad Hossein Salmani; Mohammad Javad  Salmani

doi:10.18502/jehsd.v6i2.6542

Bahman Hassan-Zadeh Department of Chemical Technology, Iranian Research and Organization for Science and Technology, Tehran, Iran.
Reza Rahmanian Department of Chemical Technology, Iranian Research and Organization for Science and Technology, Tehran, Iran.
Mohammad Hossein Salmani Environmental Science and Technology Research Center, Department of Environmental Health Engineering, School of Public Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran
Mohammad Javad Salmani DVM Student, Faculty of Veterinary Medicine, Shahid Bahonar University of Kerman, Kerman, Iran.

DOI: https://doi.org/10.18502/jehsd.v6i2.6542

Keywords: Functionalization, Malachite Green, Water Pollution, Silicon Dioxide

Abstract

Introduction: Nanoporous silica has received growing interest for its unique application potential in pollutant removal. Therefore, the development of a simple technique is required to synthesize and functionalize the nanoporous materials for industrial application.

Materials and Methods: The synthesis of nanoporous silica was investigated by the template sol-gel method, and it functionalized as an adsorbent for adsorption of malachite green. The morphology and structure of the prepared and functionalized nanoporous silica were studied using X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR), and nitrogen adsorption-desorption technique. Subsequently, the effective parameters such as solution pH, contact time, and initial concentration on the adsorption process were optimized by adsorption tests.

Results: The results showed that high-order nanoporous silica had been produced with an average diameter of 20.12 nm and average pore volume of 1.04 cm³.g⁻¹. It was found that the optimum parameters of pH, initial concentration and contact time for malachite green adsorption on nanoporous silica were 6.5, 10 mg.l^-1, and 60 min, respectively. The experimental data confirmed the Freundlich model (R² = 0.995) and the obtained kinetic data followed the pseudo-first-order equation. The maximum adsorption capacity calculated by Langmuir isotherm was found to be 116.3 mg.g^-1.

Conclusion: The high adsorption capacity showed that the acid-functionalized nanoporous silica adsorbent can be used as an adequate adsorbent to remove malachite green from aquatic environments. The large surface area can be suggested that the silica nanoporous will have potential application prospects as the adsorbent.